Yanomamite, InAsO4.2H2O, a new indium mineral from topaz-bearing greisen in the Goiás Tin Province, Brazil
Identifieur interne : 01DC65 ( Main/Repository ); précédent : 01DC64; suivant : 01DC66Yanomamite, InAsO4.2H2O, a new indium mineral from topaz-bearing greisen in the Goiás Tin Province, Brazil
Auteurs : RBID : Pascal:94-0258542Descripteurs français
- Pascal (Inist)
- Minéralisation, Greisen, Goias, Minéral nouveau, Arséniate, Indium, Forme cristalline, Couleur, Association minérale, Analyse chimique, Donnée microsonde électronique, Formule structurale, Structure cristalline, Symétrie, Groupe espace, Maille élémentaire, Constante réticulaire, Diffraction RX, Diagramme poudre, Indice réfraction, Scorodite, Variscite, Minéral secondaire, Altération hydrothermale, Microscopie électronique, Yanomamite, Donnée MEB.
English descriptors
- KwdEn :
- Goias, SEM data, X-ray diffraction analysis, X-ray powder diffraction, arsenates, cell dimensions, chemical composition, color, crystal form, crystal structure, electron microscopy, electron probe data, greisen, hydrothermal alteration, indium, mineral assemblages, mineralization, new minerals, refractive index, scorodite, secondary minerals, space groups, structural formula, symmetry, unit cell, variscite.
Abstract
Yanomamite occurs as green to yellow-green idiomorphic crystals in aggregates associated with scorodite in quartz-topaz greisen in the tin deposit of Mangabeira, Goias State, Brazil. Yanomamite crystals are always coated by a thin film of In-rich scorodite. Microprobe analyses give (wt. %): In2O3 45.8(3), Fe2O3 1.1(2), Al2O3 0.21(2), As2O5 40.1 (2), H2O 12.78 by difference, with the structural formula (In0.94Fe0.04Al0.01)AsO4. 2.02 H2O. Yanomamite is isotypic with scorodite, and belongs to the variscite series. The mineral is orthorhombic, space group Pbca, with a = 10.446(6), b = 9.085(4), c = 10.345(6) Å, V = 981.8(7) Å3, Z = 8; the synthetic Fe-free compound has a = 10.471(3), b = 9.092(2), c = 10.341(2) Å, V = 984.5(5) Å3. The strongest reflections [d in Å, (I/I0), (hkl)] of the powder diffraction pattern of natural yanomamite are: 5.70 (70)(111), 4.53 (100)(020,210), 4.163 (50)(021), 3.874 (60)(121), 3.250 (60)(122), 3.110 (50)(311), 2.656 (40)(123), 2.541 (40)(231). Dcalc = 3.876(3) g/cm3; VHN25 = 631 kg/mm2; 2VZ (meas.) = 55-76°. The average refractive index is n = 1.65. The unit-cell volume versus ionic radius of the tri- or divalent cations shows a very good correlation in the variscite isotypic series (13 arsenates, phosphates and selenates). Yanomamite and In-bearing scorodite are cogenetic, formed by alteration of early arsenopyrite and In-rich sphalerite. This replacement may be related to a hydrothermal process coeval with the main cassiterite deposition, rather than to supergene alteration
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Yanomamite, InAsO<sub>4</sub>.2H<sub>2</sub>O, a new indium mineral from topaz-bearing greisen in the Goiás Tin Province, Brazil</title><author><name sortKey="Botelho, N F" uniqKey="Botelho N">N. F. Botelho</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Univ. Brasilia, inst. geociênc.</s1><s2>Brasilia 70910</s2><s3>BRA</s3><sZ>1 aut.</sZ></inist:fA14><country>Brésil</country><wicri:noRegion>Brasilia 70910</wicri:noRegion></affiliation></author><author><name sortKey="Roger, G" uniqKey="Roger G">G. Roger</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Univ. Paris VI, lab. géologie appliquée</s1><s2>75252 Paris</s2><s3>FRA</s3><sZ>2 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Paris</settlement></placeName></affiliation></author><author><name sortKey="D Yvoire, F" uniqKey="D Yvoire F">F. D Yvoire</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Univ. Paris Sud, lab. chimie solides</s1><s2>91405 Orsay</s2><s3>FRA</s3><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Orsay</settlement></placeName></affiliation></author><author><name sortKey="Moelo, Y" uniqKey="Moelo Y">Y. Moelo</name><affiliation wicri:level="3"><inist:fA14 i1="04"><s1>CRSCM</s1><s2>45071 Orléans</s2><s3>FRA</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Centre</region><settlement type="city">Orléans</settlement></placeName></affiliation></author><author><name sortKey="Volfinger, M" uniqKey="Volfinger M">M. Volfinger</name><affiliation wicri:level="3"><inist:fA14 i1="04"><s1>CRSCM</s1><s2>45071 Orléans</s2><s3>FRA</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Centre</region><settlement type="city">Orléans</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">94-0258542</idno><date when="1994">1994</date><idno type="stanalyst">PASCAL 94-0258542 INIST</idno><idno type="RBID">Pascal:94-0258542</idno><idno type="wicri:Area/Main/Corpus">01EF47</idno><idno type="wicri:Area/Main/Repository">01DC65</idno></publicationStmt><seriesStmt><title level="j" type="abbreviated">Eur. j. mineral. : (1989)</title><title level="j" type="main">European journal of mineralogy : (1989)</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Goias</term><term>SEM data</term><term>X-ray diffraction analysis</term><term>X-ray powder diffraction</term><term>arsenates</term><term>cell dimensions</term><term>chemical composition</term><term>color</term><term>crystal form</term><term>crystal structure</term><term>electron microscopy</term><term>electron probe data</term><term>greisen</term><term>hydrothermal alteration</term><term>indium</term><term>mineral assemblages</term><term>mineralization</term><term>new minerals</term><term>refractive index</term><term>scorodite</term><term>secondary minerals</term><term>space groups</term><term>structural formula</term><term>symmetry</term><term>unit cell</term><term>variscite</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Minéralisation</term><term>Greisen</term><term>Goias</term><term>Minéral nouveau</term><term>Arséniate</term><term>Indium</term><term>Forme cristalline</term><term>Couleur</term><term>Association minérale</term><term>Analyse chimique</term><term>Donnée microsonde électronique</term><term>Formule structurale</term><term>Structure cristalline</term><term>Symétrie</term><term>Groupe espace</term><term>Maille élémentaire</term><term>Constante réticulaire</term><term>Diffraction RX</term><term>Diagramme poudre</term><term>Indice réfraction</term><term>Scorodite</term><term>Variscite</term><term>Minéral secondaire</term><term>Altération hydrothermale</term><term>Microscopie électronique</term><term>Yanomamite</term><term>Donnée MEB</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Yanomamite occurs as green to yellow-green idiomorphic crystals in aggregates associated with scorodite in quartz-topaz greisen in the tin deposit of Mangabeira, Goias State, Brazil. Yanomamite crystals are always coated by a thin film of In-rich scorodite. Microprobe analyses give (wt. %): In<sub>2</sub>O<sub>3</sub> 45.8(3), Fe<sub>2</sub>O<sub>3</sub> 1.1(2), Al<sub>2</sub>O<sub>3</sub> 0.21(2), As<sub>2</sub>O<sub>5</sub> 40.1 (2), H<sub>2</sub>O 12.78 by difference, with the structural formula (In<sub>0.94</sub>Fe<sub>0.04</sub>Al<sub>0.01</sub>)AsO<sub>4</sub>. 2.02 H<sub>2</sub>O. Yanomamite is isotypic with scorodite, and belongs to the variscite series. The mineral is orthorhombic, space group Pbca, with a = 10.446(6), b = 9.085(4), c = 10.345(6) Å, V = 981.8(7) Å<sup>3</sup>, Z = 8; the synthetic Fe-free compound has a = 10.471(3), b = 9.092(2), c = 10.341(2) Å, V = 984.5(5) Å<sup>3</sup>. The strongest reflections [d in Å, (I/I<sub>0</sub>), (hkl)] of the powder diffraction pattern of natural yanomamite are: 5.70 (70)(111), 4.53 (100)(020,210), 4.163 (50)(021), 3.874 (60)(121), 3.250 (60)(122), 3.110 (50)(311), 2.656 (40)(123), 2.541 (40)(231). D<sub>calc</sub> = 3.876(3) g/cm<sup>3</sup>; VHN<sub>25</sub> = 631 kg/mm<sup>2</sup>; 2V<sub>Z</sub> (meas.) = 55-76°. The average refractive index is n = 1.65. The unit-cell volume versus ionic radius of the tri- or divalent cations shows a very good correlation in the variscite isotypic series (13 arsenates, phosphates and selenates). Yanomamite and In-bearing scorodite are cogenetic, formed by alteration of early arsenopyrite and In-rich sphalerite. This replacement may be related to a hydrothermal process coeval with the main cassiterite deposition, rather than to supergene alteration</div></front></TEI><inist><standard h6="B"><pA><fA03 i2="1"><s0>Eur. j. mineral. : (1989)</s0></fA03><fA05><s2>6</s2></fA05><fA06><s2>2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Yanomamite, InAsO<sub>4</sub>.2H<sub>2</sub>O, a new indium mineral from topaz-bearing greisen in the Goiás Tin Province, Brazil</s1></fA08><fA11 i1="01" i2="1"><s1>BOTELHO (N. F.)</s1></fA11><fA11 i1="02" i2="1"><s1>ROGER (G.)</s1></fA11><fA11 i1="03" i2="1"><s1>D'YVOIRE (F.)</s1></fA11><fA11 i1="04" i2="1"><s1>MOELO (Y.)</s1></fA11><fA11 i1="05" i2="1"><s1>VOLFINGER (M.)</s1></fA11><fA14 i1="01"><s1>Univ. Brasilia, inst. geociênc.</s1><s2>Brasilia 70910</s2><s3>BRA</s3><sZ>1 aut.</sZ></fA14><fA14 i1="02"><s1>Univ. Paris VI, lab. géologie appliquée</s1><s2>75252 Paris</s2><s3>FRA</s3><sZ>2 aut.</sZ></fA14><fA14 i1="03"><s1>Univ. Paris Sud, lab. chimie solides</s1><s2>91405 Orsay</s2><s3>FRA</s3><sZ>3 aut.</sZ></fA14><fA14 i1="04"><s1>CRSCM</s1><s2>45071 Orléans</s2><s3>FRA</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ></fA14><fA20><s1>245-254</s1><s7>4</s7></fA20><fA21><s1>1994</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>519</s2><s5>354000025683510080</s5></fA43><fA44><s0>0000</s0></fA44><fA45><s0>1 p.</s0></fA45><fA47 i1="01" i2="1"><s0>94-0258542</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="2"><s0>European journal of mineralogy : (1989)</s0></fA64><fA66 i1="01"><s0>DEU</s0></fA66><fC01 i1="01" l="ENG"><s0>Yanomamite occurs as green to yellow-green idiomorphic crystals in aggregates associated with scorodite in quartz-topaz greisen in the tin deposit of Mangabeira, Goias State, Brazil. Yanomamite crystals are always coated by a thin film of In-rich scorodite. Microprobe analyses give (wt. %): In<sub>2</sub>O<sub>3</sub> 45.8(3), Fe<sub>2</sub>O<sub>3</sub> 1.1(2), Al<sub>2</sub>O<sub>3</sub> 0.21(2), As<sub>2</sub>O<sub>5</sub> 40.1 (2), H<sub>2</sub>O 12.78 by difference, with the structural formula (In<sub>0.94</sub>Fe<sub>0.04</sub>Al<sub>0.01</sub>)AsO<sub>4</sub>. 2.02 H<sub>2</sub>O. Yanomamite is isotypic with scorodite, and belongs to the variscite series. The mineral is orthorhombic, space group Pbca, with a = 10.446(6), b = 9.085(4), c = 10.345(6) Å, V = 981.8(7) Å<sup>3</sup>, Z = 8; the synthetic Fe-free compound has a = 10.471(3), b = 9.092(2), c = 10.341(2) Å, V = 984.5(5) Å<sup>3</sup>. The strongest reflections [d in Å, (I/I<sub>0</sub>), (hkl)] of the powder diffraction pattern of natural yanomamite are: 5.70 (70)(111), 4.53 (100)(020,210), 4.163 (50)(021), 3.874 (60)(121), 3.250 (60)(122), 3.110 (50)(311), 2.656 (40)(123), 2.541 (40)(231). D<sub>calc</sub> = 3.876(3) g/cm<sup>3</sup>; VHN<sub>25</sub> = 631 kg/mm<sup>2</sup>; 2V<sub>Z</sub> (meas.) = 55-76°. The average refractive index is n = 1.65. The unit-cell volume versus ionic radius of the tri- or divalent cations shows a very good correlation in the variscite isotypic series (13 arsenates, phosphates and selenates). Yanomamite and In-bearing scorodite are cogenetic, formed by alteration of early arsenopyrite and In-rich sphalerite. This replacement may be related to a hydrothermal process coeval with the main cassiterite deposition, rather than to supergene alteration</s0></fC01><fC02 i1="01" i2="2"><s0>220A03</s0></fC02><fC02 i1="02" i2="2"><s0>221A02</s0></fC02><fC02 i1="03" i2="X"><s0>001E01A03</s0></fC02><fC02 i1="04" i2="X"><s0>001E01E02</s0></fC02><fC03 i1="01" i2="2" l="FRE"><s0>Minéralisation</s0><s5>01</s5></fC03><fC03 i1="01" i2="2" l="ENG"><s0>mineralization</s0><s5>01</s5></fC03><fC03 i1="01" i2="2" l="SPA"><s0>Mineralización</s0><s5>01</s5></fC03><fC03 i1="02" i2="2" l="FRE"><s0>Greisen</s0><s5>02</s5></fC03><fC03 i1="02" i2="2" l="ENG"><s0>greisen</s0><s5>02</s5></fC03><fC03 i1="02" i2="2" l="SPA"><s0>Greisen</s0><s5>02</s5></fC03><fC03 i1="03" i2="2" l="FRE"><s0>Goias</s0><s2>NG</s2><s5>03</s5></fC03><fC03 i1="03" i2="2" l="ENG"><s0>Goias</s0><s2>NG</s2><s5>03</s5></fC03><fC03 i1="03" i2="2" l="SPA"><s0>Goias</s0><s2>NG</s2><s5>03</s5></fC03><fC03 i1="04" i2="2" l="FRE"><s0>Minéral nouveau</s0><s5>04</s5></fC03><fC03 i1="04" i2="2" l="ENG"><s0>new minerals</s0><s5>04</s5></fC03><fC03 i1="04" i2="2" l="SPA"><s0>Mineral nuevo</s0><s5>04</s5></fC03><fC03 i1="05" i2="2" l="FRE"><s0>Arséniate</s0><s2>NA</s2><s5>05</s5></fC03><fC03 i1="05" i2="2" l="ENG"><s0>arsenates</s0><s2>NA</s2><s5>05</s5></fC03><fC03 i1="05" i2="2" l="SPA"><s0>Arseniato</s0><s2>NA</s2><s5>05</s5></fC03><fC03 i1="06" i2="2" l="FRE"><s0>Indium</s0><s2>NC</s2><s5>06</s5></fC03><fC03 i1="06" i2="2" l="ENG"><s0>indium</s0><s2>NC</s2><s5>06</s5></fC03><fC03 i1="06" i2="2" l="SPA"><s0>Indio</s0><s2>NC</s2><s5>06</s5></fC03><fC03 i1="07" i2="2" l="FRE"><s0>Forme cristalline</s0><s5>07</s5></fC03><fC03 i1="07" i2="2" l="ENG"><s0>crystal form</s0><s5>07</s5></fC03><fC03 i1="07" i2="2" l="SPA"><s0>Forma cristalina</s0><s5>07</s5></fC03><fC03 i1="08" i2="2" l="FRE"><s0>Couleur</s0><s5>08</s5></fC03><fC03 i1="08" i2="2" l="ENG"><s0>color</s0><s5>08</s5></fC03><fC03 i1="08" i2="2" l="SPA"><s0>Color</s0><s5>08</s5></fC03><fC03 i1="09" i2="2" l="FRE"><s0>Association minérale</s0><s5>09</s5></fC03><fC03 i1="09" i2="2" l="ENG"><s0>mineral assemblages</s0><s5>09</s5></fC03><fC03 i1="09" i2="2" l="SPA"><s0>Asociación mineral</s0><s5>09</s5></fC03><fC03 i1="10" i2="2" l="FRE"><s0>Analyse chimique</s0><s5>10</s5></fC03><fC03 i1="10" i2="2" l="ENG"><s0>chemical composition</s0><s5>10</s5></fC03><fC03 i1="10" i2="2" l="SPA"><s0>Análisis químico</s0><s5>10</s5></fC03><fC03 i1="11" i2="2" l="FRE"><s0>Donnée microsonde électronique</s0><s5>11</s5></fC03><fC03 i1="11" i2="2" l="ENG"><s0>electron probe data</s0><s5>11</s5></fC03><fC03 i1="11" i2="2" l="SPA"><s0>Dato sonda electrónica</s0><s5>11</s5></fC03><fC03 i1="12" i2="2" l="FRE"><s0>Formule structurale</s0><s5>12</s5></fC03><fC03 i1="12" i2="2" l="ENG"><s0>structural formula</s0><s5>12</s5></fC03><fC03 i1="13" i2="2" l="FRE"><s0>Structure cristalline</s0><s5>13</s5></fC03><fC03 i1="13" i2="2" l="ENG"><s0>crystal structure</s0><s5>13</s5></fC03><fC03 i1="13" i2="2" l="SPA"><s0>Estructura cristalina</s0><s5>13</s5></fC03><fC03 i1="14" i2="2" l="FRE"><s0>Symétrie</s0><s5>14</s5></fC03><fC03 i1="14" i2="2" l="ENG"><s0>symmetry</s0><s5>14</s5></fC03><fC03 i1="14" i2="2" l="SPA"><s0>Simetría</s0><s5>14</s5></fC03><fC03 i1="15" i2="2" l="FRE"><s0>Groupe espace</s0><s5>15</s5></fC03><fC03 i1="15" i2="2" l="ENG"><s0>space groups</s0><s5>15</s5></fC03><fC03 i1="15" i2="2" l="SPA"><s0>Grupo espacio</s0><s5>15</s5></fC03><fC03 i1="16" i2="2" l="FRE"><s0>Maille élémentaire</s0><s5>16</s5></fC03><fC03 i1="16" i2="2" l="ENG"><s0>unit cell</s0><s5>16</s5></fC03><fC03 i1="16" i2="2" l="SPA"><s0>Celdilla cristalina</s0><s5>16</s5></fC03><fC03 i1="17" i2="2" l="FRE"><s0>Constante réticulaire</s0><s5>17</s5></fC03><fC03 i1="17" i2="2" l="ENG"><s0>cell dimensions</s0><s5>17</s5></fC03><fC03 i1="17" i2="2" l="SPA"><s0>Constante reticular</s0><s5>17</s5></fC03><fC03 i1="18" i2="2" l="FRE"><s0>Diffraction RX</s0><s5>18</s5></fC03><fC03 i1="18" i2="2" l="ENG"><s0>X-ray diffraction analysis</s0><s5>18</s5></fC03><fC03 i1="18" i2="2" l="SPA"><s0>Difracción RX</s0><s5>18</s5></fC03><fC03 i1="19" i2="2" l="FRE"><s0>Diagramme poudre</s0><s5>19</s5></fC03><fC03 i1="19" i2="2" l="ENG"><s0>X-ray powder diffraction</s0><s5>19</s5></fC03><fC03 i1="19" i2="2" l="SPA"><s0>Diagrama polvo</s0><s5>19</s5></fC03><fC03 i1="20" i2="2" l="FRE"><s0>Indice réfraction</s0><s5>20</s5></fC03><fC03 i1="20" i2="2" l="ENG"><s0>refractive index</s0><s5>20</s5></fC03><fC03 i1="20" i2="2" l="SPA"><s0>Indice refracción</s0><s5>20</s5></fC03><fC03 i1="21" i2="2" l="FRE"><s0>Scorodite</s0><s5>21</s5></fC03><fC03 i1="21" i2="2" l="ENG"><s0>scorodite</s0><s5>21</s5></fC03><fC03 i1="21" i2="2" l="SPA"><s0>Scorodita</s0><s5>21</s5></fC03><fC03 i1="22" i2="2" l="FRE"><s0>Variscite</s0><s5>22</s5></fC03><fC03 i1="22" i2="2" l="ENG"><s0>variscite</s0><s5>22</s5></fC03><fC03 i1="22" i2="2" l="SPA"><s0>Variscita</s0><s5>22</s5></fC03><fC03 i1="23" i2="2" l="FRE"><s0>Minéral secondaire</s0><s5>23</s5></fC03><fC03 i1="23" i2="2" l="ENG"><s0>secondary minerals</s0><s5>23</s5></fC03><fC03 i1="23" i2="2" l="SPA"><s0>Mineral secundario</s0><s5>23</s5></fC03><fC03 i1="24" i2="2" l="FRE"><s0>Altération hydrothermale</s0><s5>24</s5></fC03><fC03 i1="24" i2="2" l="ENG"><s0>hydrothermal alteration</s0><s5>24</s5></fC03><fC03 i1="24" i2="2" l="SPA"><s0>Alteración hidrotermal</s0><s5>24</s5></fC03><fC03 i1="25" i2="2" l="FRE"><s0>Microscopie électronique</s0><s5>25</s5></fC03><fC03 i1="25" i2="2" l="ENG"><s0>electron microscopy</s0><s5>25</s5></fC03><fC03 i1="25" i2="2" l="SPA"><s0>Microscopía electrónica</s0><s5>25</s5></fC03><fC03 i1="26" i2="2" l="FRE"><s0>Yanomamite</s0><s4>INC</s4><s5>52</s5></fC03><fC03 i1="27" i2="2" l="FRE"><s0>Donnée MEB</s0><s5>61</s5></fC03><fC03 i1="27" i2="2" l="ENG"><s0>SEM data</s0><s5>61</s5></fC03><fC03 i1="27" i2="2" l="SPA"><s0>Dato MEB</s0><s5>61</s5></fC03><fC06><s0>ILS</s0><s0>TAS</s0><s0>AN</s0></fC06><fC07 i1="01" i2="2" l="FRE"><s0>Brésil</s0><s2>NG</s2></fC07><fC07 i1="01" i2="2" l="ENG"><s0>Brazil</s0><s2>NG</s2></fC07><fC07 i1="01" i2="2" l="SPA"><s0>Brasil</s0><s2>NG</s2></fC07><fC07 i1="02" i2="2" l="FRE"><s0>Amérique du Sud</s0><s2>NG</s2></fC07><fC07 i1="02" i2="2" l="ENG"><s0>South America</s0><s2>NG</s2></fC07><fC07 i1="02" i2="2" l="SPA"><s0>America del sur</s0><s2>NG</s2></fC07><fN21><s1>125</s1></fN21></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV3
|flux= Main
|étape= Repository
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|texte= Yanomamite, InAsO4.2H2O, a new indium mineral from topaz-bearing greisen in the Goiás Tin Province, Brazil
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